刘 坤

职称：副教授

性别：男

职务：教师

办公电话：

移动电话：13975028920

家庭电话：13975026312

家庭住址：湖南理工大学

电子邮箱：12016008@hnist.edu.cn

工作学习经历

主讲课程

《物理化学》《物理化学实验》《高分子化学》

研究方向

高分子合成：主要从事共轭烯烃活性可控阴离子聚合和序列调控研究，重点涉及功能弹性体合成/改性，官能化锂系聚合物，高端碳氢树脂等石油化工高分子材料和生物基高分子材料定制。

乙烯裂解碳五资源综合利用：采用廉价的乙烯裂解碳五馏分中间戊二烯/环戊二烯/异戊二烯为原料合成系列高附加值高分子材料用单体和功能助剂等。

主要学术成果

工学博士，硕士生导师，湖南省骨干教师，湖南省石油化工优秀工程师，岳阳市高校协会优秀专家，岳阳市科技科技特派员，山东星顺新材料有限公司云溪区域负责人，中石化湖南石化聚合物材料合成所所长。主要研究领域集中在石油化工高分子材料合成与改性；纵向课题集中在共轭烯烃和环内酯类单体阴离子序列可控聚合方面，主持国家自然科学青年基金1项，湖南省自然科学基金2项，湖南省教育厅重点项目和优秀青年项目2项；横向课题主要集中在中石化乙烯裂解碳五资源优化利用系列课题，承担中石化湖南石化课题多项，2026年官能化SSBR技术在湖南石化实现500吨产业化。在ACS polymers Au, European polymer journal, Polymer Chemistry, ACS Omega, Polymer等国际高分子权威期刊上发表SCI论文30余篇，专利20余件。目前承担《物理化学》和《高分子化学》课程，获批国家级和湖南省《物理化学》混合一流本科课程，指导中国国际大学生创新创业大赛国家级铜奖2项，湖南省大挑项目一等奖和创新创业大赛二等奖多项。

承担项目：

1、间戊二烯异构体活性可控离子/自由基交替共聚合研究，国家自然科学基金青年项目(21901070)，主持，2020-2022。

2、C5衍生-戊内酯高效绿色制备及其活性可控阴离子开环聚合研究，湖南省自然科学基金面上项目（2023JJ30279），主持，2023-2025。

3、新型多用途双锂引发体系制备及其应用探索研究，湖南省自然科学基金青年项目(2019JJ50213)，主持，2020-2022。

4、间戊二烯高反1.4-选择性碳负离子聚合及功能化，湖南省教育厅优秀青年项目（20B263），主持，2020-2022。

5、新型胺基功能化溶聚丁苯橡胶可控制备及性能研究，山东星顺新材料股份有限公司横向项目（SDXS-0001），主持，2023-2025。

6、吸附-萃取联用对复杂溶液中低浓度金、钯、铂高效富集与精细分离，国家自然科学基金重点项目（U20A20268），参与，2021-2024。

7、聚合物材料合成所，中石化湖南石化产学研平台项目（10850000-18-ZC0609-0001），主持，2018-2023。

8、苯乙烯-间戊二烯嵌段共聚物选择性加氢研究，中石化湖南石化横向项目（10850000-19-ZC0607-0001），主持，2020-2023。

9、聚合级间戊二烯精制新工艺研究，中石化湖南石化横向项目（10850000-19-ZC0613-0005），主持，2020-2023。

10、以环戊烷为锂系聚合物生产过程溶剂的探索研究，中石化湖南石化横向项目（10850000-20-ZC0607-0007），主持，2020-2021。

代表性论文：

[1] Liu Kun, Long Yao, Tan  Haoyun, Han Xupeng, Zhou Jiahao, Gao Xihao, Wei Shana, Chen Zhifang, Shang Tingxuan, Tan Jiaping, Liu Meilin, Yi Wen-Jun*, Gu Xiaoxing, Li Lijun*. Quantitative epoxidation study of high vinyl polybutadiene and tertiary amine-functionalized polybutadiene synthesized by LAP, ACS Polymers Au, 2026, ASAP.

[2] Kun Liu, Yao Long, Xupeng Han, Yixin Xiang, Haoyun Tan, Jingjiao Gui, Gaoyun Peng, Xihao Gao, Shana Wei, Zhifang Chen, Wenjun Yi, Xiaoxing Gu, Lijun Li*. Anionic terpolymerization of butadiene with 1,3-pentadiene and styrene to afford well-defined gradient copolymer with tunable trans-1,4 units. European Polymer Journal, 2026, DOI: 10.1016/j.eurpolymj.2026.114916

[3] Yao Long , Jiahao Zhou, Xupeng Han, Min Zhang, Yayan Wang, Jiaping Tan, Meilin Liu, Lijun Li*, Kun Liu*. Facile synthesis of well-defined gradient 4-vinylbenzyl-piperidine/β-myrcene copolymer via living and controlled anionic copolymerization under mild conditions. Polymer, 2026, 361, 130393.

[4] Yao Long, Xupeng Han, Jiahao Zhou, Yixin Xiang, Jingjiao Gui, Yi Xiao, Tingxuan Shang, Qiqi Dai, Kun Liu*, Lijun Li*. Facile synthesis of quantitatively tertiary-amine functionalized poly(styrene-co-1,3-pentadiene) copolymers with controlled narrow composition distributions by LAP. Polymer chemistry, 2026, 17, 1909-1920.

[5] Kun Liu, Xupeng Han, Jiahao Zhou, Yao Long, Min Zhang, Yayan Wang, Jiaping Tan, Meilin Liu, Lijun Li, Yali Li. Bifunctional group distribution and gradient structure resulting from the anionic copolymerization of styrene and vinylbenzyl N,N-allylmethylamine. Polymer Chemistry, 2026, DOI:10.1039/D6PY00394J.

[6] Kun Liu, Xupeng Han, Jiahao Zhou, Yao Long, Min Zhang, Yayan Wang, Fengli Xie, Zhe Xiao, Wenjun Yi, Lijun Li, Yali Li. Highly efficient complete hydrogenation of (polystyrene-b-poly(styrene-alt-1,3-pentadiene)-b-polystyrene) triblock copolymer using a low-cost Ni-based catalyst. ACS Omega, 2026, DOI:10.1021/acsomega.6c02834.

[7] Yao Long, Xupeng Han, Jiahao Zhou, Yixin Xiang, Haoyu Tan, Jingjiao Gui, Gaoyun Peng, Xihao Gao, Shana Wei, Kun Liu*, Lijun Li*. The effect of 1,2-bis(4-ethyl-piperazin-1-yl)ethane on the living anionic copolymerization of 1,3-pentadiene and isoprene. European Polymer Journal, 2026, DOI: 10.1016/j.eurpolymj.2026.114710.

[8] Kun Liu*, Yao Long, Xupeng Han, Qiqi Dai, Shihan Ding, Yang Yang, Yi Xiao, Yujie Wang, Xinyu Han, Xihao Gao, Shana Wei, Jing Cao*, Wenjun Yi,  Xiaoxing Gu and Lijun Li*. Anionic copolymerization of 1,3-pentadiene and styrene via weak polar additives to modulate copolymer sequences. Polymer, 2026, 342, 129368.

[9] Yangyang, Qiqi Dai, Yao Long, Yujie Wang, Zhifang Chen, Yi Yang, Le Zhou, Yi Xiao, Xinyu Han, Jiexun Zhang, Shihan Ding, Kun Liu*, Lijun Li*.The effect of 1,2-dipiperidinoethane derivatives on the composition and hydride sequence distribution in the LAP of styrene and isoprene. Polymer Chemistry, 2025, 16(43):4755-4763.

[10] Kun Liu, Qiqi Dai, Jiexun Zhang, Yawen Fu, Xupeng Han, Yao Long, Yanyan Zhang, Yi Yang, Wenjun Yi, Lijun Li*. Anionic terpolymerization of 1,3-pentadiene, para-methyl styrene and para-tert-butylstyrene to produce alternating-random sequence copolymer with tunable composition. European Polymer Journal, 2025, 224: 113684.

[11] Qiqi Dai, Yao Long, Xupeng Han, Yang Yang, Yi Yang, Yawen Fu, Wenjun Yi, Xiaoxing Gu, Kun Liu* and Lijun Li*. Facile synthesis of functionalized high vinyl polybutadiene by using 1,2-dipiperidinoethane derivatives as polar modifiers. Polymer Chemistry, 2025, 16(17): 1997-2006.

[12] Kun Liu*, Qiqi Dai, Yi Xiao, Xupeng Han, Yujie Wang, Yao Long, Zhifang Chen, Wenjun Yi, Xiaoxing Gu, Lijun Li*. Facile synthesis of tertiary amine functionalized liquid polyisoprene rubber by LAP with 1,2-Dipiperidinoethane derivatives as modifier. European Polymer Journal, 2025, 235: 114020.

[13] Xupeng Han, Yang Yang, Yao long, Zhifang Chen, Yujie Wang, Qiqi Dai, Wenjun Yi, Lijun Li*, Kun Liu*. Highly Efficient and Quantitative Epoxidation of the Poly(1,3-pentadiene) with Controlled Microstructure Synthesized by Living Anionic Polymerization. Polymer, 2025: 129036.

[14] Qiqi Dai, Yao Long, Xupeng Han, Kun Liu*, Yang Yang, Yawen Fu, Yanyan Zhang, Yi Yang, Bingbing Zhang, Wenjun Yi, Zan Yang, Lijun Li*. The synthesis of well-defined and constant composition terpolymer containing multi-alternating modules via LAP. Polymer Bulletin, 2025.

[15] Qiqi Dai, Yawen Fu, Haoyun Tan, Yanyan Zhang, Yi Yang, Jundong Xu, Wenjun Yi, Ruixuan Tan, Kun Liu*, Lijun Li*, Zan Yang*. Living anionic copolymerization of 1,3-pentadiene isomers with alpha-methylstyrene in the presence of 2,2-di(2-tetrahydrofuryl)propane. Polymer, 2024, 312: 127629.

[16] Haoyun Deng, Zhixiong Yang, Mengzhen Zhou, Encai Ou, Yanbing Lu, Qiulan Zhou*, Kun Liu*, Weijian Xu*. Anionic polymerization of (Z)-1,3-pentadiene using Ba/Al/Li trimetallic initiators to synthesize crystalline high trans-1,4-polypentadiene. Polymer, 2024, 315: 127841.

[17] Yawen Fu, Qiqi Dai, Haoyun Tan, Xupeng Han, Bingbing Zhang, Qiaoqiao Xiong, Wenjun Yi, Zan Yang*, Lijun Li*, Kun Liu*. The influence of myrcene on anionic copolymerization of 1,3-pentadiene and styrene. European Polymer Journal, 2024, 221: 113507.

[18] Kun Liu*, Yawen Fu, Qiqi Dai, Haoyun Tan, Zhuowei Gu, Qiaoqiao Xiong, Shuai Yang, Mingming Zhang, Jianxiang Feng*, Wenjun Yi, Lijun Li*. Synthesis, characterization and quantitative epoxidation-modification of a novel high-transparency S(SP)S symmetrical triblock copolymer with alternating mid-block by LAP method. European Polymer Journal, 2024, 207: 112812.

[19] Yawen Fu, Shuai Yang, Qiaoqiao Xiong, Zhuowei Gu, Qiqi Dai, Haoyun Tan, Le Zhou, Menghan Geng, Fengli Xie, Wenjun Yi, Lijun Li*, Kun Liu*. Synthesis, kinetic study and characterization of C5-dienes/styrene copolymers via living anionic polymerization in cyclopentyl methyl ether solvent. Polymer International, 2023, 73: 326-336.

[20] Kun Liu, Qiaoqiao Xiong, Zhuowei Gu, Feng Zhang, Yawen Fu, Fengli Xie, Wenjun Yi, An Li*, Jundong Xu*, Lijun Li*. Catalyst-free and visible light-induced RAFT alternating polymerization of 1,3-pentadiene isomers and maleic anhydride. European Polymer Journal, 2023, 196: 112292.

[21] Qiaoqiao Xiong, Shuai Yang, Chengjun Peng, Fengli Xie, Zhuowei Gu, Yawen Fu, Haoyun Tan, QiQi Dai, Wenjun Yi, Lijun Li*, Kun Liu*. Epoxidation modification of strictly alternating copolymer via living and controlled anionic alternating copolymerization of 1,3-pentadiene and styrene derivatives. Journal of Polymer Research, 2023, 30(8): 326.

[22] Qiaoqiao Xiong†, Yawen Fu†, Jundong Xu†, Zhuowei Gu, Chengjun Peng, Haoyun Tan, Qiqi Dai, Yujie Cao, Fengli Xie, An Li, Wenjun Yi, Lijun Li*, Kun Liu*. 1,3-Pentadiene-Assistant Living Anionic Terpolymerization: Composition Impact on Kinetics and Microstructure Sequence Primary Analysis. Polymers, 2023, 15: 2191.

[23] Kun Liu, Qiaoqiao Xiong, Zhuowei Gu, Fengli Xie, Feng Zhang, Shuai Yang, An Li, Jundong Xu*, Wenjun Yi, Lijun Li*. Highly efficient one-pot synthesis of anhydride-riched terpolymers from radical dual-alternating strategy. Journal of Polymer Research, 2023, 30(6): 192.

[24] Cen Zhang^#, Kun Liu^#, Yicen Zhang, Linchao Mu, Zhiwen Zhang, Jing Huang, Yanze Wang, Tao Yang, Jing Cao*, Congshan Zhou. Co-promoted few-layer and defect-rich MoS2 for enhanced hydrodeoxygenation of p-cresol. Applied Catalysis A: General, 2021, 621: 118175.

[25] An Li, Xinyang Wang, Yuhang Li, Caiwu Luo, Jiance Zhang, Kun Liu*, Cen Zhang*, Congshan Zhou*. A Novel Gemini Sulfonic Ionic Liquid Immobilized MCM-41 as Efficient Catalyst for Doebner-Von Miller Reaction to Quinoline. ChemCatChem, 2021, 13(17): 3772-3780.

[26] Kun Liu, Min Sun, Fengli Xie, Cainan Hu, Zan Yang, An Li*, JinKui Xia, Xu Qiu, Xu Wang, Haoyun Deng. 1:1 Alternating and 1:2 Sequence-Controlled Radical Copolymerization of 1,3-Pentadiene Isomers with Maleic Anhydride/N-Phenylalkyl Maleimide. Polymer Chemistry, 2020,11, 675-681.

[27] Kun Liu, Feng Zhang, Min Sun, Fengli Xie, Shuhang Ying, Zan Yang, Congshan Zhou*, Jinkui Xia, An Li*. Thermally Stable and Well-Defined Pentadiene-Derived Copolymers Prepared by Anionic Alternating Copolymerization and Subsequent Controlled Postmodification. Macromolecular Chemistry and Physics, 2020, 221, 2000161-2000169.

[28] An Li, Caiwu Luo, Yong Liu, Lijun Li, Ying Lin, Kun Liu*, Congshan Zhou*. Zn-promoted Hβ Zeolite for Gas-phase Catalyzed Aza-heterocyclicaromatization of Acrolein Dimethyl Acetal and Aniline to Quinolones. Molecular Catalysis, 2020, 486,110833-110842.

[29] Zan Yang, Yemei Liang, An Li, Kun Liu*, Lijun Li, Tao Yang*, Congshan Zhou*. One-Pot Synthesis of 5 Acyl-1,2,3-Thiadiazoles from Enaminones, Tosylhydrazine, and Elemental Sulfur under Transition-Metal-Free Conditions. The Journal of Organic Chemistry，2019, 84, 24, 16262–16267.

[30] Zan Yang, Jiaqi Zhang, Liping Hu, An Li, Lijun Li, Kun Liu*, Tao Yang*, Congshan Zhou*. Electrochemical HI-mediated Intermolecular C-N Bond Formation to Synthesize Imidazoles from Aryl Ketones and Benzylamines. The Journal of Organic Chemistry，2020, 85, 9, 5952–5958.

[31] Zan Yang, Jiaqi Zhang, Liping Hu, Lijun Li, Kun Liu*, Tao Yang, Congshan Zhou. Electrochemical Oxidative Intramolecular N-S Bond Formation:Synthesis of 3-Substituted-5-Amino-1,2,4-Thiadiazoles. The Journal of Organic Chemistry，2020, 85, 5, 3358–3363.

[32] An Li, CaiWu Luo, Fen Wu, ShuQin Zheng, LiJun Li, JianCe Zhang, Liang Chen, Kun Liu*, Congshan Zhou*. Mesoporous HBeta Zeolite via Zeolitic Dissolution- Recrystallization Successive Treatment for Vapor-Phase Doebner-Von Miller Reaction to Quinolines New J. Chem. 2020，DOI 10.1039/D0NJ04539J.

[33] Kun Liu, An Li, Zan Yang, AoLin Jiang, FengLi Xie, Shan Li, JinKui Xia, ZhenYin She, KeWen Tang*, CongShan Zhou*. Synthesis of Strictly Alternating Copolymers by Living Carbanionic Copolymerization of Diphenylethylene with 1,3-Pentadiene Isomers. Polymer Chemistry, 2019, 10: 1787-1794.

[34] Kun Liu, Lei Ren, Qing He, Wei Jian Xu*. Synthesis of Copolymers by Living Carbanionic Alternating Copolymerization. Macromolecular Rapid Communications, 2016, 37(9):752-758.

[35] Kun Liu, Qing He, Lei Ren, Lai Jiang Gong, Jin Long Hu, En Cai Ou, Wei Jian Xu*. Synthesis and characterization of the well-defined polypentadiene via living anionic polymerization of (E)-1,3-pentadiene. Polymer, 2016, 89, 28-40.

[36] Kun Liu, Qing He, Lei Ren, Feng Xu, Wei Jian Xu. Living anionic polymerization of (E)‐1,3‐pentadiene and (Z)‐1,3‐pentadiene isomers. Journal of Polymer Science Part A: Polymer Chemistry, 2016, 54(15):2291-2301.

授权专利：

[1] 刘 坤等，一种共轭二烯烃-苯乙烯类共聚物及其制备方法和应用、抗菌高分子材料及其应用，CN202411657534.1。

[2] 刘坤等，种胺基功能化的透明抗冲击苯乙烯-间戊二烯共聚树脂及其制备方法，CN202311195483.0。

[3] 刘 坤等，苯乙烯-间戊二烯-苯乙烯嵌段共聚物及其合成方法和应用，CN202010609463.3。

[4] 肖哲，刘坤等，一种透明型全氢化聚苯乙烯-间戊二烯树脂及其制备方法，CN202311251368.0。

个人简介

刘坤，副教授，化工博士，硕士生导师，湖南省石油化工优秀工程师，岳阳市高校协会优秀专家，岳阳市科技科技特派员，山东星顺新材料有限公司云溪区域负责人，中石化湖南石化聚合物材料合成所所长。主要研究领域集中在石油化工高分子材料合成与改性；纵向课题集中在共轭烯烃和环内酯类单体阴离子序列可控聚合方面，承担国家自然科学青年基金1项，湖南省自然科学基金2项，湖南省教育厅重点项目和优秀青年项目2项；横向课题主要集中在中石化乙烯裂解碳五资源优化利用系列课题，承担中石化湖南石化课题5项，在国际高分子权威期刊发表SCI论文 30余篇，专利20余件。目前承担《物理化学》和《高分子化学》课程，主持国家级和湖南省《物理化学》混合一流本科课程，指导中国国际大学生创新创业大赛国家级铜奖2项，湖南省大挑项目一等奖和创新创业大赛二等奖多项。