化学化工学院硕士研究生导师
姓 名:熊碧权
学 科:化学工程与技术
研究方向:工业催化;精细有机化工;
电话/传真:18817009076
电子邮件:xiongbiquan@126.com
个人和研究方向简介:
1987年生,男,博士,讲师,硕士生导师。
申请国家发明专利7项,授权2项;以第一作者在ACS Catal(IF = 10.6), Chem. Eur. J. (IF = 5.731), Adv. Synth. Catal (IF = 5.663), Eur. J. Org. Chem. (IF = 3.065), Tetrahedron (IF = 2.675)等国际著名期刊发表论文9篇。2016年获得国家自然科学基金青年项目1项,湖南省教育厅科学研究项目青年项目1项等资助。。
代表性论著:
(1): B.-Q. Xiong, X. Feng, Q. Ye, L. Zhu, T. Chen, Y. Zhou, C.-T. Au, S.-F. Yin, Direct Aerobic Oxidative Esterification and Arylation of P(O)-OH Compounds with Alcohols and Diaryliodonium Triflates. ACS. Catal. 2015, 5, 537-543.
(2): B.-Q. Xiong, R. Shen, M. Goto, S.-F. Yin, L.-B. Han, Highly Selective 1,4- and 1,6-Addition of P(O)-H Compounds to p-Quinones: A Divergent Method for the Synthesis of C- and O-Phosphoryl Hydroquinone Derivatives. Chem. Eur. J. 2012, 18, 16902-16910.
(3): B.-Q. Xiong, M. Li, Y. Liu, Y. Zhou, C. Zhao, M. Goto, S.-F. Yin, L.-B. Han, Stereoselective Synthesis of Phosphoryl-Substituted Phenols. Adv. Synth. Catal. 2014, 356, 781-794.
(4): B.-Q. Xiong, L. Zhu, X. Feng, J. Lei, T. Chen, Y. Zhou, L.-B. Han, C.-T. Au, S.-F. Yin, Direct Amidation of Carboxylic Acids with Tertiary Amines: Amide Formation over Copper Catalysts through C–N Bond Cleavage. Eur. J. Org. Chem. 2014, 4244-4247.
(5): B.-Q. Xiong, Y. Zhou, C. Zhao, M. Goto, S.-F. Yin, L.-B. Han, Systematic study for the stereochemistry of the AthertoneTodd reaction. Tetrahedron. 2013, 69, 9373-9380.
(6): B.-Q. Xiong, Q. Ye, X. Feng, L. Zhu, T. Chen, Y. Zhou, C.-T. Au, S.-F. Yin, Base-promoted O-deprotonation/alkylation reaction of P(O)-OH compounds with alkyl halides. Tetrahedron. 2014, 70, 9057-9063.
(7): B.-Q. Xiong, K. Zeng, S. Zhang, Y. Zhou, C.-T. Au, S.-F. Yin, Copper-catalyzed direct esterification of P(O)-OH compounds with phenols. Tetrahedron, 2015, 71, 9293-9298.
(8): B.-Q. Xiong, C. Hu, H. Li, C. Zhou, P. Zhang, Y. Liu, K. Tang, CDI-promoted direct esterification of P(O)-OH compounds with phenols. Tetrahedron Letters, 2017, 58, 2482-2486.
(9): B.-Q. Xiong, C. Hu, J. Gu, C. Yang, P. Zhang, Y. Liu, K. Tang, Efficient and Controllable Esterification of P(O)-OH Compounds Using Uronium-Based Salts. Chemistryselect, 2017, 2, 3376-3380.